Brian was a participant in the Understanding Chemical Bonding project. He was interviewed during the first year of his college A level course (equivalent to Y12 of the English school system). Brian was shown, and asked about, a sequence of images representing atoms, molecules and other sub-microscopic structures of the kinds commonly used in chemistry teaching. He was shown a simple representation of a covalent molecule:
Any idea what that’s meant to be, number 2?
Hydrogen molecule.
Why, how do you recognise that as being a hydrogen molecule?
Because there’s two atoms with one electron in each shell.
Uh hm. Er, what, what’s going on here, in this region here, where these lines seem to meet?
Bonding.
That’s bonding. So there’s some sort of bonding there is there?
Yeah.
Can you tell me anything about that bonding?
It’s covalent bonding.
So, so what’s covalent bonding, then?
The electrons are shared to create a full outer shell.
Okay, so that’s an example of covalent bonding, so can you tell me how many bonds there are there?
One.
There’s one covalent bond?
Yeah.
Right, what exactly is a covalent bond?
It’s where electrons are shared, almost, roughly equally, between the two atoms.
So that’s what we’d call a covalent bond?
Yeah.
The idea that a covalent bond is the sharing of electrons to allow atoms to obtain full electron shells is a very common way of discussing covalent bonding, drawing upon the full shells explanatory principle, where a 'need' for completing electron shells is seen as the impetus for bonding, reactions, ion formation etc. This principle is the basis of a common alternative conceptual framework, the octet rule framework.
For some students, such ideas are the extent of their ways of discussing bonding phenomena. However, despite his defining the covalent bond in this way, continued questioning revealed that Brian was able to think about the bond in terms of physical interactions
Okay. And why do they, why do these two atoms stay stuck together like that? Why don’t they just pull apart?
Because of the bond.
So how does the bond do that?
(Pause, c.13s)
Is it by electrostatic forces?
Is it - so how do you think that works then?
I’m not sure.
Can you see anything there that would give rise to electrostatic forces?
The electrons.
Right so the electrons, they’re charged are they?
Yeah. Negatively.
Negatively charged - anything else?
(Pause, c.8s)
The protons in the nucleus are positively charged.
Uh hm. And so would that give rise to any electronic interactions?
Yeah.
So where would there be, sort of any kind of, any kind of force involved here is there?
By the bond.
So where would there be force, can you show me where there would be force?
By the, in the bond, down here.
So the force is localised in there, is it?
The erm, protons would be repelling each other, they’d be attracted by the electrons, so they’re keep them at a set distance.
It seemed that Brian could discuss the bond as due to electrical interactions, although his initial ('instinctive') response was to explain the bond in terms of electrons shared to fill electron shells. Often students learn to explain bonds as electron sharing in school science, and this becomes a habitual way of talking and thinking by the time the progress to college level study.
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Dr Keith S Taber kst24@cam.ac.uk
University of Cambridge Faculty of Education
© Keith S Taber, 2012