Particles in ice and water have different characteristics

Making a link between particle identity and change of state

Keith S. Taber

Image by Colin Behrens from Pixabay 

Bill was a participant in the Understanding Science Project. Interviews allow learners to talk about their understanding of science topics, and so to some extent allow the researcher to gauge how well integrated or fragmented a learner's ideas are.

Occasionally there is a sense of 'seeing the cogs turn', where it appears that the interview is not just an opportunity for reporting knowledge, but a genuine site for knowledge construction (on behalf of the students, as well as the researcher) as the learner's ideas seem to change and develop in the interview itself.

One example of this occurred when Bill, a Y7 student, explained what he had learnt about particles in solids, liquids and gases. Bill seemed unsure if the particles in different states of matter were different, or just had different properties. However, when asked about a change of state Bill related heating to changes in the way particles were arranged, and seemed to realise this implied the particles themselves were the same when a substance changes state. Bill seemed to be making a link between particle identity and change of state through the process of answering the researcher's questions.

Bill introduced the idea of particles when talking about what he had learn about the states of matter

Well there's three groups, solids, liquids and gases.

So how do you know if something is a solid, a liquid or a gas?

Well, solids they stay same shape and their particles only move a tiny bit.

This point was followed up later in the interview.

So, you said that solids contain particles,

Yeah.

They don't move very much?

No.

And you've told me that ice is a solid?

Yeah.

So if I put those two things together, that tells me that ice should contain particles?

Yeah.

Yeah, and you said that liquids contain particles? Did you say they move, what did you say about the particles in liquids?

Er, they're quite, they're further apart, than the ones in erm solids, so they erm, they try and take the shape, they move away, but the volume of the water doesn't change. It just moves.

Okay. So the particles in the liquid, they seem to be doing something a bit different to particles in a solid?

Yeah.

What about the particles in the gas?

The gas, they, they're really, they're far apart and they try and expand.

Does that include steam, because you said steam was a gas?

Yeah.

Yeah?

I think.

So, we've got particles in ice?

Yeah.

And they have certain characteristics?

Yeah.

And there are particles in water?

Yeah.

That have different characteristics?

Yeah.

And particles in gas, which have different characteristics again?

Yeah.

Okay. So, are they different particles, then?

N-, I'm not sure.

There are several interesting points here. Bill reports that the particles in liquids are "further apart, than the ones in … solids". This is generally true when comparing the same substance, but not always – so ice floats in water for example. Bill uses anthropomorphic language, reporting that particles try to do things.

Of particular interest here, is that at this point in the interview Bill did not seem to have a clear idea about whether particles kept their identify across changes of state. However, the next interview question seemed to trigger a response which clarified this issue for him:

So have the solid particles, sort of gone away, when we make the liquid, and we've got liquid particles instead?

No {said firmly}, when a solid goes to a liquid, the heat gives the particles energy to spread about, and then when its a liquid, it's got even more energy to spread out into a gas.

So we're talking about the same particles, but behaving differently, in a solid to a liquid to a gas?

Yeah.

That's very clear.

It appears Bill had learnt a model of what happened to the particles when a solid melted, but had not previously appreciated the consequences of this idea for the identity of particles across the different states of matter. Being cued to bring to mind his model of the effect of heating on the particles during melting seemed to make it obvious to him that there were not different particles in the different states (for the same substance), where he had seemed quite uncertain about this a few moments earlier.

Whilst this has to remain something of a speculation, the series of questions used in research interviews can be quite similar in nature to the sequences of questions used in the method of instruction known as Socratic dialogue – a method that Plato reported being used by Socrates to lead someone towards an insight.

So, a 'eureka' moment, perhaps?

Author: Keith

Former school and college science teacher, teacher educator, research supervisor, and research methods lecturer. Emeritus Professor of Science Education at the University of Cambridge.

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