insight - Science-Education-Research

Single bonds are different to covalent bonds

Single bonds are different to covalent bonds or ionic bonds

Keith S. Taber

Annie was a participant in the Understanding Chemical Bonding project. She was interviewed near the start of her college 'A level' course (equivalent to Y12 of the English school system). Annie was shown, and asked about, a sequence of images representing atoms, molecules and other sub-microscopic structures of the kinds commonl y used in chemistry teaching. She was shown a representation of the resonance between three canonical forms of BF3, sometimes used as away of reflection polar bonding. She had just seen another image representing resonance in the ethanoate ion, and had suggested that it contained a double bond. She had earlier in the interview referred to covalent bonding and ionic bonding, and after introducing the ideas of double bond, suggested that a double bond is different to a covalent bond.

What about diagram 14?…
Oh.
(pause, c.13s)
Seems to be different arrangements. Of the three, or two elements.
Uh hm.
(pause, c.3s)
Which are joined by single bonds.
What, where, what single, what sorry are joined by single bonds?
All the F to the B to the F. Are single bonds they are not double like before. [i.e., a figure discussed earlier in the interview]
So are they covalent bonds? Or ionic bonds, or? Or are single bonds something different again?
Single bonds are different.

This reflected her earlier comment to the effect that a double bond is different to a covalent bond, suggesting that she did not appreciate how covalent bonds are considered to be singular or multiple.

However, as I checked what she was telling me, Annie's account seemed to shift.

They're different to double bonds?
Yeah.
And are they different to covalent bonds?
No 'cause you probably get covalent bonds which are single bonds.

So single bonds, just moments before said to different to covalent bonds, were now 'probably' capable of being covalent. As she continued to answer questions, Annie decided these were 'probably' just alternative terms.

So covalent bonds and single bonds, is that another word for the same thing?
Yeah, probably. But they can probably occur in different, things like in organic you talk about single bonds more than you talk about covalent, and then like in inorganic you talk about covalent bond, more than you talk about single bonding or double bonding.
So you think that maybe inorganic things, like sort of, >> copper iodide or something like that, that would tend to be more concerned with covalent bonds?
< Yeah. < Yeah.
But if you were doing organic things like, I don't know, erm, ethane, >> that's more likely to have single bonds in.
< Yeah. < Yeah.
So single bonds are more likely to occur in carbon compounds.
Yeah.
And covalent bonds are more likely to occur in some other type of compound?
Yeah. Sort of you've got different terminology, like you could probably use single bonds to refer to something in inorganic, but when you are talking about the structures and that, it's easier to talk about single bonds and double bonds, rather than saying that's got a covalent bond or that's got an ionic bond.

Annie's explanation did not seem to be a fully thought-out position. It was not consistent with the way she had earlier reported there being five covalent bonds and one double bond in an ethanoate ion.

It seems likely that in the context of the research interview, where being asked directly about these points, Annie was forced to make explicit the reasons she tended to label particular bonds in specific ways. The interview questions may have acted like Socratic questioning, a kind of scaffolding, leading to new insights. Only in this context did she realise that the single and double bonds her organic chemistry lecturer talked about might actually be referring to the same entities as the covalent bonds her inorganic chemistry lecturer talked about.

It would probably not have occurred to Annie's lecturers (of which, I was one) that she would not realise that single and double bonds were covalent bonds. It may well have been that if she had been taught by the same lecturer in both areas, the tendency to refer to single and multiple bonds in organic compounds (where most bonds were primarily covalent) and to focus on the covalent-ionic dissension in inorganic compounds (where degree of polarity in bonds was a main theme of teaching) would still have lead to the same confusion. Later in the interview, Annie commented that:

if I use ionic or covalent I'm talking about, sort of like a general, bond, but if I use double or single bonds, that's mainly organic, because sort of it represents, sort of the sharing, 'cause like you draw all the molecules out more.

This might be considered an example of fragmentation learning impediment, where a student does not make a link that the teacher is likely to assume is obvious.

How plants get their food to grow and make energy

Respiration produces energy, but photosynthesis produces glucose which produces energy

Keith S. Taber

Mandy was a participant in the Understanding Science Project. When I spoke to her in Y10 (i.e. when she was c.14 year old) she told me that photosynthesis was one of the topics she was studying in science. So I asked her about photosynthesis:

So, photosynthesis. If I knew nothing at all about photosynthesis, how would you explain that to me?
It's how plants get their food to grow and – stuff, and make energy
So how do they make their energy, then?
Well, they make glucose, which has energy in it.
How does the energy get in the glucose?
Erm, I don't know.
It's just there is it?
Yeah, it's just stored energy

I was particularly interested to see if Mandy understood about the role of photosynthesis in plant nutrition and energy metabolism.

Why do you think it is called photosynthesis, because that's a kind of complicated name?
Isn't photo, something to do with light, and they use light to – get the energy.
So how do they do that then?
In the plant they've got chlorophyll which absorbs the light, hm, that sort of thing.
What does it do once it absorbs the light?
Erm.
Does that mean it shines brightly?
No, I , erm – I don't know

Mandy explained that the chlorophyll was in the cells, especially in the plant's leaves. But I was not very clear on whether she had a good understanding of photosynthesis in terms of energy.

Do you make your food?
Not the way plants do.
…
So where does the energy come from in your food then?
It's stored energy.
How did it get in to the food? How was it stored there?
Erm.
[c. 2s pause]
I don't know.

At this point it seemed Mandy was not connecting the energy 'in' food either directly or indirectly with photosynthesis.

Okay. What kind of thing do you like to eat?
Erm, pasta.
Do you think there is any energy value in pasta? Any energy stored in the pasta?
Has lots of carbohydrates, which is energy.
…
So do you think there is energy within the carbohydrate then?
Yeah.
Stored energy.
Yeah.
So how do you think that got there, who stored it?
(laughs) I don't know.

Again, the impression was that Mandy was not linking the energy value of food with photosynthesis. The reference to carbohydrates being energy seemed (given the wider context of the interview) to be imprecise use of language, rather than a genuine alternative conception.

So do you go to like the Co-op and buy a packet of pasta. Or mum does I expect?
Yeah.
Yeah. So do you think, sort of, the Co-op are sort of putting energy in the other end, before they send it down to the shop?
No, it comes from 'cause pasta's made from like flour, and that comes from wheat, and then that uses photosynthesis.

Now it seemed that it was quite clear to Mandy that photosynthesis was responsible for the energy stored in the pasta. It was not clear why she had not suggested this before, but it seemed she could make the connection between the food people eat and photosynthesis. Perhaps (it seems quite likely) she had previously been aware of this and it initially did not 'come to mind', and then at some point during this sequences of questions there was a 'bringing to mind' of the link. Alternatively, it may have been a new insight reached when challenged to respond to the interview questions.

So you don't need to photosynthesise to get energy?
No.
No, how do you get your energy then?
We respire.
Is that different then?
Yeah.
So what's respire then, what do you do when you respire?
We use oxygen to, and glucose to release energy.
Do plants respire?
Yes.
So when do you respire, when you are going to go for a run or something, is that when you respire, when you need the energy?
No, you are respiring all the time.

Mandy suggested that plants mainly respire at night because they are photosynthesising during the day. (Read 'Plants mainly respire at night'.)

So is there any relationship do you think between photosynthesis and respiration?
Erm respiration uses oxygen – and glucose and it produces er carbon dioxide and water, whereas photosynthesis uses carbon dioxide and water, and produces oxygen and glucose.
So it's quite a, quite a strong relationship then?
Yeah.
Yeah, and did you say that energy was involved in that somewhere?
Yeah, in respiration, they produce energy.
What about in photosynthesis, does that produce energy?
That produces glucose, which produces the energy.
I see, so there is no energy involved in the photosynthesis equation, but there is in the glucose?
Yeah.

Respiration does not 'produce' energy of course, but if it had the question about whether photosynthesis also produced energy might have been expected to elicit a response about photosynthesis 'using' energy or something similar, to give the kind of symmetry that would be consistent with conservation of energy (a process and its reverse can not both 'produce' energy). 'Produce' energy might have meant 'release' energy in which case it might be expected the reverse process should 'capture' or 'store' it.

Mandy appreciated the relationship between photosynthetic and respiration in terms of substances, but had an asymmetric notion of how energy was involved.

Mandy appeared to be having difficult appreciating the symmetrical arrangement between photosynthesis and respiration because she was not clear how energy was transformed in photosynthesis and respiration. Although she seemed to have the components of the scientific narrative, she did not seem to fully appreciate how the absorption of light was in effect 'capturing' energy that could be 'stored' in glucose till needed. At this stage in her learning she seemed to have grasped quite a lot of the relevant ideas, but not quite integrated them all coherently.

Particles in ice and water have different characteristics

Making a link between particle identity and change of state

Keith S. Taber

Bill was a participant in the Understanding Science Project. Interviews allow learners to talk about their understanding of science topics, and so to some extent allow the researcher to gauge how well integrated or fragmented a learner's ideas are.

Occasionally there is a sense of 'seeing the cogs turn', where it appears that the interview is not just an opportunity for reporting knowledge, but a genuine site for knowledge construction (on behalf of the students, as well as the researcher) as the learner's ideas seem to change and develop in the interview itself.

One example of this occurred when Bill, a Y7 student, explained what he had learnt about particles in solids, liquids and gases. Bill seemed unsure if the particles in different states of matter were different, or just had different properties. However, when asked about a change of state Bill related heating to changes in the way particles were arranged, and seemed to realise this implied the particles themselves were the same when a substance changes state. Bill seemed to be making a link between particle identity and change of state through the process of answering the researcher's questions.

Bill introduced the idea of particles when talking about what he had learn about the states of matter

Well there's three groups, solids, liquids and gases.
So how do you know if something is a solid, a liquid or a gas?
Well, solids they stay same shape and their particles only move a tiny bit.

This point was followed up later in the interview.

So, you said that solids contain particles,
Yeah.
They don't move very much?
No.
And you've told me that ice is a solid?
Yeah.
So if I put those two things together, that tells me that ice should contain particles?
Yeah.
Yeah, and you said that liquids contain particles? Did you say they move, what did you say about the particles in liquids?
Er, they're quite, they're further apart, than the ones in erm solids, so they erm, they try and take the shape, they move away, but the volume of the water doesn't change. It just moves.
Okay. So the particles in the liquid, they seem to be doing something a bit different to particles in a solid?
Yeah.
What about the particles in the gas?
The gas, they, they're really, they're far apart and they try and expand.
Does that include steam, because you said steam was a gas?
Yeah.
Yeah?
I think.
So, we've got particles in ice?
Yeah.
And they have certain characteristics?
Yeah.
And there are particles in water?
Yeah.
That have different characteristics?
Yeah.
And particles in gas, which have different characteristics again?
Yeah.
Okay. So, are they different particles, then?
N-, I'm not sure.

There are several interesting points here. Bill reports that the particles in liquids are "further apart, than the ones in … solids". This is generally true when comparing the same substance, but not always – so ice floats in water for example. Bill uses anthropomorphic language, reporting that particles try to do things.

Of particular interest here, is that at this point in the interview Bill did not seem to have a clear idea about whether particles kept their identify across changes of state. However, the next interview question seemed to trigger a response which clarified this issue for him:

So have the solid particles, sort of gone away, when we make the liquid, and we've got liquid particles instead?
No {said firmly}, when a solid goes to a liquid, the heat gives the particles energy to spread about, and then when its a liquid, it's got even more energy to spread out into a gas.
So we're talking about the same particles, but behaving differently, in a solid to a liquid to a gas?
Yeah.
That's very clear.

It appears Bill had learnt a model of what happened to the particles when a solid melted, but had not previously appreciated the consequences of this idea for the identity of particles across the different states of matter. Being cued to bring to mind his model of the effect of heating on the particles during melting seemed to make it obvious to him that there were not different particles in the different states (for the same substance), where he had seemed quite uncertain about this a few moments earlier.

Whilst this has to remain something of a speculation, the series of questions used in research interviews can be quite similar in nature to the sequences of questions used in the method of instruction known as Socratic dialogue – a method that Plato reported being used by Socrates to lead someone towards an insight.

So, a 'eureka' moment, perhaps?

Molecules are like a jigsaw

Keith S. Taber

Tim was a participant in the Understanding Science Project. When Tim was interviewed in the first term of his 'A level' (college level) physics course he had been studying the topic of materials with one of his teachers, and "at the moment we're doing about why some materials are brittle, and some aren't, and about the molecules". When Tim was asked about the molecules, he compared molecules to the pieces in a jigsaw:

Interviewer: So what's a molecule?
Tim: Erm it's like a bit of a particle, so, something that makes up something.
I: Have you got any examples?
T: Of a molecule?
I: Yeah, something that makes up something.
T: Erm, like the wood in the table is made out of wood molecules.
I: I see. So, that's one type of molecule, is it, a wood molecule? And there are other types of molecule?
T: Yes it's a bit like a jigsaw, like when you put all the, like you need to put the…, you put them all together to make – something.
I: I see, yeah. So, if I wanted to be really awkward, in what way is it like a jigsaw?
T: Erm, well they sort of fit together, like in a jigsaw some bits are sort of straight and have nice parallel, a nice parallel microstructure, and some, some jigsaws have funny bits that don't fit together quite as nicely.
I: I see. So are there some ways it's not like a jigsaw?
T: Yeah. (Tim laughs.) Well, erm, I dunno, it's like a jigsaw in the way that the bits fit together to make something, to make something, but then again, I dunno.
I: I mean, I quite like this idea of it being like a jigsaw – I was wondering whether, whether you had got that from somewhere, or that's just something you'd come up with?
T: No I just thought about it, just then.
I: Oh that's really creative.
T: It's quite random actually. (laughs)

Tim's comments about a molecules being a bit of a particle was followed up later in the interview, and it transpired he was not sure if a molecule is a bit of a particle – or vice versa.*

So when asked to explain about molecules in materials, Tim used an apparently spontaneous analogy of this being like a jigsaw, with different types of pieces that fitted together. Moreover, he also seemed to recognise that different materials had molecules that fitted together more or less readily, and materials could also be considered to have similar diversity. Tim described this as being 'random', which seems unfair as the analogy clearly has merit, but presumably saw it this way as the comparison had apparently appeared in his consciousness unexpectedly (i.e., the thought had 'popped into his mind', as a kind of insight.)

Tim seemed a little phased by being asked to explain the negative features of the analogy – and this may reflect the tendency to focus on the positive aspects of an analogy, rather than its limitations. Analogy has the potential to channel student thinking in inappropriate directions (e.g., as associative learning impediments) when not considered critically. However, analogies also have potential to help 'make the unfamiliar familiar' and so can be a powerful learning tool.