Covalent bonding is sharing electrons

It's covalent bonding where the electrons are shared to create a full outer shell

Keith S. Taber

Brian was a participant in the Understanding Chemical Bonding project. He was interviewed during the first year of his college 'A level' course (equivalent to Y12 of the English school system). Brian was shown, and asked about, a sequence of images representing atoms, molecules and other sub-microscopic structures of the kinds commonly used in chemistry teaching. He was shown a simple representation of a covalent molecule:

Focal figure ('2') presented to Brian

Any idea what that's meant to be, number 2?

Hydrogen molecule.

Why, how do you recognise that as being a hydrogen molecule?

Because there's two atoms with one electron in each shell.

Uh hm. Er, what, what's going on here, in this region here, where these lines seem to meet?

Bonding.

That's bonding. So there's some sort of bonding there is there?

Yeah.

Can you tell me anything about that bonding?

It's covalent bonding.

So, so what's covalent bonding, then?

The electrons are shared to create a full outer shell.

Okay, so that's an example of covalent bonding, so can you tell me how many bonds there are there?

One.

There's one covalent bond?

Yeah.

Right, what exactly is a covalent bond?

It's where electrons are shared, almost, roughly equally, between the two atoms.

So that's what we'd call a covalent bond?

Yeah.

So according to Brian, covalent bonding is where "the electrons are shared to create a full outer shell". The idea that a covalent bond is the sharing of electrons to allow atoms to obtain full electron shells is a very common way of discussing covalent bonding, drawing upon the full shells explanatory principle, where a 'need' for completing electron shells is seen as the impetus for bonding, reactions, ion formation etc. This principle is the basis of a common alternative conceptual framework, the octet rule framework.

For some students, such ideas are the extent of their ways of discussing bonding phenomena. However, despite Brian defining the covalent bond in this way, continued questioning revealed that he was able to think about the bond in terms of physical interactions

Okay. And why do they, why do these two atoms stay stuck together like that? Why don't they just pull apart?

Because of the bond.

So how does the bond do that?

(Pause, c.13s)

Is it by electrostatic forces?

Is it – so how do you think that works then?

I'm not sure.

The long pause suggests that Brian did not have a ready formed response for such a question. It seems here that 'electrostatic forces' is little more than a guess, if perhaps an informed guess because charges and forces had features in chemistry. A pause of about 13 seconds is quite a lacuna in a conversation. In a classroom context teachers are advised to give students thinking time rather than expecting (or accepting) immediate responses. Yet, in many classrooms, 13 seconds of 'dead air' (to borrow a phrase from broadcasting) from the teacher night be taken as an invitation to retune attention to another station.

Even in an interview situation the interviewer's instinct may be to move on to a another question, but in situations where a researcher is confident that waiting is not stressful to the participant, it is sometimes productive to give thinking time.

Another issue relating to interviewing is the use of 'leading questions'. Teachers as interviewers sometimes slip between researcher and teacher roles, and may be tempted to teach rather than explore thinking.

Yet, the very act of interviewing is an intervention in the learners' thinking, in that whatever an interviewer tells us is in the context of the conversation set up by the interviewer, and the participant may have ideas they would not have done without that particular context. In any case, learning is not generally a once off event, as school learning relies on physiological process long after the initial teaching event to consolidate learning, and this is supported by 'revision'. Each time a memory is reactivated it is strengthened (and potentially changed).

So the research interview is a learning experience no matter how careful the researcher is. Therefore the idea of leading questions is much more nuanced that a binary distinction between those questions which are leading and those that are not. So rather than completely avoiding leading questions, the researcher should (a) use open-ended questions initially to best understand the ideas the learner most easily beings to mind; (b) be aware of the degree of 'scaffolding' that Socratic questioning can contribute to the construction of a learners' answer. [Read about the idea of scaffolding learning here.] The interview continued:

Can you see anything there that would give rise to electrostatic forces?

The electrons.

Right so the electrons, they're charged are they?

Yeah. Negatively.

Negatively charged – anything else?

(Pause, c.8s)

The protons in the nucleus are positively charged.

Uh hm. And so would that give rise to any electronic interactions?

Yeah.

So where would there be, sort of any kind of, any kind of force involved here is there?

By the bond.

So where would there be force, can you show me where there would be force?

By the, in the bond, down here.

So the force is localised in there, is it?

The erm, protons would be repelling each other, they'd be attracted by the electrons, so they're keep them at a set distance.

It seemed that Brian could discuss the bond as due to electrical interactions, although his initial ('instinctive') response was to explain the bond in terms of electrons shared to fill electron shells. Although the researcher channelled Brian to think about the potential source of any electrical interactions, this was only after Brian had himself conjectured the role of 'electrostatic forces.'

Often students learn to 'explain' bonds as electron sharing in school science (although arguably this is a rather limited form of explanation), and this becomes a habitual way of talking and thinking by the time they progress to college level study.

A sodium atom wants to donate its electron to another atom

Keith S. Taber

Lovesh was a participant in the Understanding Chemical Bonding Project, studying 'A level' chemistry in a further education college. He was interviewed in his second year of the two year A level course, and was presented with focal figure 1 (below). He recognised figure 1 as showing a "sodium, atom", and was asked about its stability:

Is that a stable species, do you think?

Erm (pause, c.3s) No, because it hasn't got a, a full outer – electron shell, outer electron shell hasn't got eight electrons in.

Lovesh shared the common notion that an atom without a full outer shell / octet of electrons would be unstable compared with the corresponding ion with a full outer shell / octet of electrons. When comparing isolated atoms with the corresponding ions this is seldom the case, yet this is a common alternative conception about chemical stability. A sodium ion can be considered stable in an ionic lattice, or when hydrated in solution, but does not spontaneously ionise as the outer shell electron is attracted to the atom's positive core. Ionisation only occurs when sufficient work is done to overcome this attraction.

Lovesh was demonstrating the common full shells explanatory principle alternative conception which is central to the common octet rule framework – an alternative conceptual framework reflecting very common 'misconceptions' found among learners studying chemistry.

Lovesh was asked what would happen to the atom that he considered unstable:

So if it's not stable, what would tend to happen to that, do you think?

It will wanna donate the electron to another atom.

Right, when you say 'it wants to donate' it?

Erm. (pause, c.3s) Well because that outer electron is less attracted to the nucleus, erm it is, it can easily be transferred, attracted by another atom.

Lovesh's first response here used the term 'wanna' (want to) which if take literally suggests the atom has desires and preferences. This is an example of anthropomorphism, imbuing objects with human-like traits. Using anthropomorphic explanations is a common feature of the octet rule framework which often leads to students talking as if atoms deliberately act to get full outer electron shells.

It has been suggested that such anthropomorphism may be either 'strong'- where the learner is offering an explanation they find convincing – or 'weak' if they are using language metaphorically, just as a figure of speech.

In this case, when Lovesh's use of the notion of 'wants' was queried he was able to shift to a different language register in terms of the action of physics forces – the electron being attracted elsewhere. Lovesh had clearly acquired an appropriate way of thinking about the interactions between atoms, but his spontaneous explanation was couched in anthropomorphic terms. Although in this case the anthropomorphism was of a weak form, the habitual use of this kind of language may come to stand in place of offering a scientifically acceptable account.