In ionic bonding, they both want to get full outer shells

Keith S. Taber

Mohammed was a participant in the Understanding Science Project. When interviewed in the first term of his upper secondary (GCSE) science course (in Y10), he told me he had been learning about ionic bonding in one of his science classes. Mohammed had quite a clear idea about ionic bonding, which he described in terms of the interactions of two atoms:

And you said in chemistry you've been doing about electron arrangements [electronic configurations], and ionic bonding.

Yeah.

So what's ionic bonding, then?

Ionic bonding is when, like let's say, a sodium atom and take a chlorine atom, which make salt if they react. What happens is – the sodium atom has one electron on its outer shell, and the chlorine atom has seven, now they both want to get full outer shells, so if I er let's say move the electron from the sodium to the chlorine, then the chlorine would have a full outer shell because it would have eight, and because it's lost that shell the sodium will also have eight.

This account of ionic bonding is a common one, although it is inconsistent with the scientific model. A key problem here is that the driving force for bond formation is seen in terms of atoms wanting to complete their electron shells (the 'full shells explanatory principle'). Mohammed's explanation here uses anthropomorphism, as it treats the individual atoms as though they are alive and sentient, acting to meet their own needs – "they both want to get full outer shells".

When Mohammed was probed, he related a full outer shell to atomic stability (a central feature of the full shells explanatory principle).

Okay. How do you know they want full outer shells?

Because it makes them more stable.

Why does it make them more stable?

(pause, c.1 s)

Erm. (Why do electrons?*) (* sotto voce – apparently said to himself)

(pause, c.2s)

Er, because they don't react as much with other elements if they have a full outer shell.

I see.

They don't react.

There is an interesting contrast here between Mohammed's instant response that full shells "makes them more stable", and the long pause as he thought about why this might be so.

His response reflects something quite common in students' explanations n that a student asked why X is the case may respond by explaining why they think X is the case. (That is, as if an appropriate answer to the question "why is it raining so heavily?" would be "because I got soaked through getting here", i.e. actually responding to the question "how do you know that it is raining heavily?")

Such responses seem to be logically flawed, but of course may be a mis-perception of the question being asked (so the learner is answering the question they thought was asked), or (possibly the case here) substituting a response to a related question as a strategy adopted when aware that one cannot provide a satisfactory response to the actual question posed.

The anthropomorphic aspect of his earlier answer was probed:

How do the atoms know that they need to get a full outer shell, they want to get a full outer shell? Do they know about this stability thing?

Not really.

No?

It's just what happens.

Oh, I see, it's just what happens?

Yeah.

So although Mohammed used an anthropomorphic explanation, it seemed he did not mean this literally. (It may seem strange to suggest a 14 year old might consider atoms alive and sentient, but research suggests this is sometimes so!) This has been described as weak anthropomorphism, where the anthropomorphism is only used as a figure of speech. However, such language can act as a grounded learning impediment because if it becomes habitual it can stand in place of a scientific explanation (thus giving no reason to seek a canonical scientific understanding).

I went on to ask Mohammed about the formation of salt in the process he had described.

Author: Keith

Former school and college science teacher, teacher educator, research supervisor, and research methods lecturer. Emeritus Professor of Science Education at the University of Cambridge.

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