Liquid iron stays a liquid when heated

Keith S. Taber

Sophia was a participant in the Understanding Science Project. In Y7, Sophia had told me that if molten iron was heated "some of it would evaporate but not all of it, 'cause it's not like water and it's more heavy". She thought only "a little" of the iron would evaporate to give iron vapour: The rest "really just stays as a liquid". [See 'Iron is too heavy to completely evaporate'.]

Just over a year later (in Y8) Sophia had been studying "that different erm substances have different freezing and melting and boiling points, and some aren't like a liquid at room temperatures, some are a solid and some are a gas and things like that".

Give me an example of something else that's a solid at room temperature?

Iron.

Do you think iron would have a melting point?

Yeah.

Yeah, and if I, what would I get if I, if I heated iron to its melting point?

It would become a liquid.

And why would it do that?

Because it's got so hot that particles – they have spread out or something?

So what do you think would happen if I heated the iron liquid?

It would stay a liquid.

No matter how much I heated it?

It might, I don't know if it would become a vapour.

Can you get iron vapour?

No, I don't think so.

You don't think so?

No.

So it seems that Sophia had shifted from accepting that iron would partially evaporate (when learning about the particle model of the different states), to considering that iron (probably) can not become a vapour. The notion of iron as a gas is not something we can readily imagine, and apparently did not seem very feasible. In part this might be because we think of iron the material (a metal, which cannot exist in in the vapour phase) rather than as a substance that can take different material forms.

It seems Sophia's prior knowledge of iron the material was working against her learning about iron the substance, an examples of a grounded learning impediment where prior knowledge impedes new learning.

In Y7 Sophia had seemed to have a hybrid conception where having been taught a general model of the states of matter and changes of state, she accepted the counter-intuitive idea that iron could evaporate, but thought that (unlike in the case of water) it could not completely evaporate . This might have been a 'stepping stone' between not accepting iron could be in the gaseous state and fitting it within the general model that all substances will when progressively heated first melt and then evaporate (or boil) as long as they did not decompose first.

However, it seems that a year later Sophia was actually more resistant to the idea that iron could exist as vapour and so now she thought molten iron would remain liquid no matter how much it was heated. If anything, she had reverted to a more intuitive understanding. This is not that strange: it has been shown that apparent conceptual gains which are counter to strongly held intuitions that are brought about by teaching episodes that are not regularly reinforced can drop away as the time since teaching increases. Conceptual change does not always involve shifts towards the scientific accounts.

[Sophia was in lower secondary school when I talked to her about this: but I was also told by a much older student that the idea of iron turning into a gas sounds weird.]

Author: Keith

Former school and college science teacher, teacher educator, research supervisor, and research methods lecturer. Emeritus Professor of Science Education at the University of Cambridge.

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