science teaching - Science-Education-Research

Covalent bonding is when atoms share electrons to combine into one whole thing

Keith S. Taber

Umar was a participant in the Understanding Chemical Bonding project. When I spoke to him in the first term of his advanced level chemistry course he identified figure 2 (below) as representing a hydrogen molecule, with covalent bonding.

UCB Figure 2 (for interview-about-instances technique)

Can you tell me what you think that's meant to represent?
Er, two hy-, a hydrogen molecule, 'cause it's like they've got one electron, in the only one shell, and they're joined together, a covalent bonding, and they're sharing it.
So what is a covalent bond exactly?
When they share electrons.
When you share electrons?
Yeah.

So when Umar thought of covalent bonding he seemed to primarily associate this with the notion of 'sharing' of electrons. The idea that atoms can 'share' anything could be considered an example of anthropomorphism, but this is a common metaphor that is widely used in discussing bonding.

The 'sharing' notion is however little more than a descriptive label, and has limited explanatory power. Acceptable explanations of the bond would draw upon scientific concepts, such as electrical forces, or atomic orbital overlaps allowing the formation of lower energy molecular orbitals. I probed Umar to see how he understood the nature of the covalent bond.

Or do you think they're stuck together?
I think they're quite strong together, covalent is quite a strong bond.
So that will hold them together will it?
Yeah.

Umar certainly saw the bond as a strong linkage of some kind, but so far my questions had not revealed how he understood the bond to hold the molecule together.

Well how does it do that?
It's like, they're joined together, 'cause first of all they just had two atoms with one electron each, and now they're sharing two electrons between them. So it's quite strong.
Oh, why's that?
Because the the the actual, when they share them they're like combined into like one sort of whole thing, instead of two separate atoms.
Right, so the, so the bond, which is the sharing of two electrons, that holds them together,
Yeah.
to make one thing, which we've called a molecule.
Yeah.

So at this point in Umar's course he seemed to conceptualise the covalent bonding as electron sharing and saw the action of sharing to inherently hold the molecule together, and seemed to be satisfied with that as an explanation for the bond. This discussion took place early in the interview, before we then discussed a whole range of other images. Near the very end of the interview I returned to ask about figure 2 again (see Sharing the same shell and electron makes them more joined together like one)*.

An element needs a certain number of electrons

An element needs a certain amount of electrons in the outer shell

Keith S. Taber

Bert was a participant in the Understanding Science project. In Y10 Bert was talking about how he had been studying electrolysis in class. Bill had described electrolysis as "where different elements are, are taken out from a compound", but it transpired that Bert thought that "a compound is just a lot of different elements put together"*. He seemed to have a tentative understanding that electrolysis could only be used to separate elements in some compounds.

if they're positive and negative then they would be able to be separated into different ones.
So some things are, some things aren't?
Yeah, it matters how many electrons that they have.
Ah. [pause, c.3s] So have you got any examples of things that you know would definitely be positive and negative?
Well I could tell you what happens.
Yeah, go on then.
Well erm, well if a, if an element gives away, electrons, then it becomes positive. But if it gains, then it becomes negative. Because the electrons are negative, so if they gain more, they just go a bit negative.
Yeah. So why would an element give away or gain some electrons? Why would it do that?
Because erm, it needs a certain amount of electrons in the outer shell. It matters on what part of the periodic table they are.
Okay, let me be really awkward. Why does it need a certain number of electrons in the outer shell?
[Pause, c.2 s]
Erm, well, I don't know. It just –

So Bert thought that an element "needs a certain amount of electrons in the outer shell" depending upon it's position in the periodic table, but he did not seem to recall having been given any reason why this was. The use of the term 'needs' is an example of anthropomorphism, which is commonly used by students talking about atoms and molecules. Often this derives from language used by teachers to help humanise the science, and provide a way for students to make sense of the abstract ideas. If Bert comes to feel this is a sufficient explanation, then talk of what an element needs can come to stand in place of learning a more scientifically acceptable explanation, and so can act as a grounded learning impediment.

References to atoms needing a certain number of electrons is often used as an explanatory principle (the full shells explanatory principle) considered to explain why bonding occurs, why reactions occur and so forth.

Bert's final comment in the short extract above seems to reflect a sense of 'well that's just the way the world is'. It is inevitable that if we keep asking someone a sequence of 'well, why is that' question when they tell us about their understanding of the world, they eventually reach the limits of their understanding. (This tendency has been labelled 'the explanatory gestalt of essence'.) Ultimately, even science has to accept the possibility that eventually we reach answers and can not longer explain further – that's just the way the world is. Research suggests that some students seem to reach the 'it's just natural' or 'well that's just the way it is' point when teachers might hope they would be looking for further levels of explanation. This may link to when phenomena fit well with the learner's intuitive understanding of the world, or tacit knowledge.

Bert's reference to an element needing a certain amount of electrons in the outer shell also seems to confuse description at two different levels: he explicitly refer to substance (element), when he seems to mean a quanticle (atom). Element refers to the substance, at the macroscopic level of materials that can be handled in the laboratory, whilst an atom of the element (which might better be considered to gain or lose electrons) is part of the theoretical model of matter at a submicroscopic level, used by chemists as a basis for explaining much macroscopic, observed behaviour of samples of substances.

Electrical resistance depends upon density

Keith S. Taber

Amy was a participant in the Understanding Science project.

Amy (Y10) suggested that a circuit was "a thing containing wires and components which electricity can pass through…it has to contain a battery as well". She thought that electricity could pass through "most things".

For Amy "resistance is anything which kind of provides a barrier that, which the current has to pass through, slowing down the current in a circuit", and she thought about this in terms of the analogy with water in pipes: "we've been taught the water tank and pipe running round it… just imagine the water like flowing through a pipe, and obviously like, if the pipe becomes smaller at one point, erm, the water flow has to slow down, and that's meant to represent the resistance of something".

So for Amy, charge flow was impeded by physical barriers effectively blocking its way. She made the logical association with the density of a material, on the basis that a material with densely packed particles would have limited space for the charge to flow:

So electricity would "not very easily" pass through a wooden bench "because wood is quite a dense material and the particles in it are quite closely bonded".

In air, however, the particles were "not as dense as a solid". When asked if that meant that electricity can pass through air quite easily, Amy replied: "yeah, I think so".

Amy's connection between the density of particles and the ease with which charge could flow is a logical one, but unfortunately involves a misunderstanding of how charge flows through materials, i.e., from a canonical scientific perspective, thinking about the charge flowing through gaps between particles is unhelpful here. (So this can be considered an alternative conception.) This seems to be a creative associative learning impediment, where prior learning (here, the spacing of quanticles in different materials) is applied, but in a context beyond its range of application.

A dusty analogy – a visual demonstration of ionisation in a mass spectrometer

Keith S. Taber

Amy was a participant in the Understanding Science project. She was interviewed when she had just started her 'A level' (i.e., college) chemistry, and one of the topics that the course had started with was mass spectrometry. She gave me a very detailed account of what she had been taught, despite both casting doubt on the logic of parts of the account, and of the accuracy of her own recollection (see Amy's account of mass spectrometry *). One of the unconvincing aspects of the new topic seemed to be the way positive ions were produced by bombarding atoms with (negative) electrons – although she had clearly picked up the point.

She reported that her teacher had demonstrated this point with an analogy. She told me that the teacher was using a lot of analogies, and she seemed to find them a little silly, implying that this analogy was not helpful. This particular example involved a board duster and two matchboxes. One matchbox sat on the duster, and was knocked off by the other matchbox being projected at it.

I thought this was quite interesting, as Amy did think the formation of positive ions was counter-intuitive, but had remembered that this is what happened, and seemed to both remember and understand the use of the analogy – even though she was somewhat dismissive of it. I didn't get the chance to explore the issue at the time, but wondered if this was an example of a student maybe not appreciating the role of models and analogies (and simulation) in science itself, and so feeling that using such a device in teaching science was a little 'naff'.

Amy's explanation of the stupid-sounding bit

Amy was dismissive of the teacher's analogical teaching model, even though she seemed to have remembered what he was illustrating:

I mean there was a couple of bits there that you didn't seem too sure about like, like er you know you sort of, you seemed to almost disown the fact that this electron gun is going to make these things into positive ions, you didn't seem very convinced by that?
Erm – I dunno if it's that I'm not convinced it just sounds weird, because it's like erm (pause, c.2s) I dunno, well it's like it's not something which you can see,
No.
and it's like, I dunno, he did this sort of example using a duster and two matchboxes, and, which wasn't very good, so.(Amy was laughing at this point)
Tell me about that then, how does that work? You see I know a bit about this, I don't know about the duster and the matchboxes.
Like no disrespect to our teacher but he uses these analogies, a duster being an atom with matchboxes being the electrons and something, and them being knocked off, because, yeah.
So he threw a matchbox at a duster that had a matchbox and he knocked the matchbox off the duster?
Pretty much.
See, it works for me,
(Amy laughs)
and you've remembered it?
Well, yeah, but – yeah.
…
Erm, So you've got this neutral atom, and you're firing negative electrons at it?
Yeah.
Now if you say that to somebody who doesn't know anything about what's going to happen, what do you think might happen if you fire negative electrons at a neutral atom?, what might you get?
A negative ion.
That's what you'd expect I think, isn't it, … well obviously you are firing negative things at it, so you will get negative. But in fact that's not what seems to happen. So he was trying to explain to you why firing negative things, at something neutral, you might end up with something positive. 'cause that's not obvious and logical, is it?
Yeah.
So if you throw a matchbox at a duster that contains a matchbox, you might knock the match box off?
Yeah (Amy laughs).

There is clearly a 'cultural' difference here, between the interviewer (a science teacher by background) and the interviewee (the learner), in that the interviewer 'got' the use of the demonstration as a pretty neat physical analogy, whereas the student clearly was dismissive. In this case Amy's lack of engagement with the modelling process did not seem to limit her learning, but her attitude demonstrated a lack of awareness of the status and roles of models in science (and in learning science) which has potential to act as a deficiency learning impediment if she cannot see how teaching models and analogies can help form mental models of scientific systems.