An element needs a certain number of electrons

An element needs a certain amount of electrons in the outer shell

Keith S. Taber

Bert was a participant in the Understanding Science project. In Y10 Bert was talking about how he had been studying electrolysis in class. Bill had described electrolysis as "where different elements are, are taken out from a compound", but it transpired that Bert thought that "a compound is just a lot of different elements put together"*. He seemed to have a tentative understanding that electrolysis could only be used to separate elements in some compounds.

if they're positive and negative then they would be able to be separated into different ones.

So some things are, some things aren't?

Yeah, it matters how many electrons that they have.

Ah. [pause, c.3s] So have you got any examples of things that you know would definitely be positive and negative?

Well I could tell you what happens.

Yeah, go on then.

Well erm, well if a, if an element gives away, electrons, then it becomes positive. But if it gains, then it becomes negative. Because the electrons are negative, so if they gain more, they just go a bit negative.

Yeah. So why would an element give away or gain some electrons? Why would it do that?

Because erm, it needs a certain amount of electrons in the outer shell. It matters on what part of the periodic table they are.

Okay, let me be really awkward. Why does it need a certain number of electrons in the outer shell?

[Pause, c.2 s]

Erm, well, I don't know. It just – 

So Bert thought that an element "needs a certain amount of electrons in the outer shell" depending upon it's position in the periodic table, but he did not seem to recall having been given any reason why this was. The use of the term 'needs' is an example of anthropomorphism, which is commonly used by students talking about atoms and molecules. Often this derives from language used by teachers to help humanise the science, and provide a way for students to make sense of the abstract ideas. If Bert comes to feel this is a sufficient explanation, then talk of what an element needs can come to stand in place of learning a more scientifically acceptable explanation, and so can act as a grounded learning impediment.

References to atoms needing a certain number of electrons is often used as an explanatory principle (the full shells explanatory principle) considered to explain why bonding occurs, why reactions occur and so forth.

Bert's final comment in the short extract above seems to reflect a sense of 'well that's just the way the world is'. It is inevitable that if we keep asking someone a sequence of 'well, why is that' question when they tell us about their understanding of the world, they eventually reach the limits of their understanding. (This tendency has been labelled 'the explanatory gestalt of essence'.) Ultimately, even science has to accept the possibility that eventually we reach answers and can not longer explain further – that's just the way the world is. Research suggests that some students seem to reach the 'it's just natural' or 'well that's just the way it is' point when teachers might hope they would be looking for further levels of explanation. This may link to when phenomena fit well with the learner's intuitive understanding of the world, or tacit knowledge.

Bert's reference to an element needing a certain amount of electrons in the outer shell also seems to confuse description at two different levels: he explicitly refer to substance (element), when he seems to mean a quanticle (atom). Element refers to the substance, at the macroscopic level of materials that can be handled in the laboratory, whilst an atom of the element (which might better be considered to gain or lose electrons) is part of the theoretical model of matter at a submicroscopic level, used by chemists as a basis for explaining much macroscopic, observed behaviour of samples of substances.


A compound is just a lot of different elements put together

Keith S. Taber

Bert was a participant in the Understanding Science project. When interviewed in Y10 he reported that he had been studying electrolysis in chemistry:

"that's where different elements are, are taken out from a compoundthere's a positive anode and a negative cathode. And what it does it attracts the positive part of the compound to the negative cathode, and the negative part goes to the positive , to, you know, so that they can erm get the different elements in the different places, so they can just have one element on its own".

To fully understand what this means from a chemical context the learner needs to appreciate the chemical distinction between elements, compounds and mixtures, so I asked Bert what he thought a compound was:

It's erm, it's er two, er you know, it's just a lot of different elements put together – to create just one.

So if I went and got some elements, let's say I went and got a little file of carbon, a little file of sulphur, a little file of copper, er a little file of magnesium and I were to mix them into a beaker, maybe get a glass rod, give it a good stir, er, give me a compound?

Erm, so it's carbon, erm, carbon, sulphur, magne¬. Carbon, er – What's the fourth one?

Carbon, sulphur, magnesium and copper I think I said.

And copper. All right, erm. Copper, copper sulphate and – and carbon, and I think carbon and magnesium might go just as elements.

Okay, so if I ignored the carbon and magnesium,

Yeah.

if I took some copper and some sulphur,

Yeah.

and mixed them up together,

Yeah.

then I'd get copper sulphate.

Yeah.

And that's a compound now?

Yeah.

In chemistry there is a crucial difference between a mixture and a compound: one which it appeared Bert had not at this point acquired. Presumably his chemistry teacher, in teaching the topic of electrolysis was assuming students in the class would apply prior learning about the difference between elements and compounds, so as to appreciate the significance of electrolysis as a technique which brings about an energetically unfavourable chemical change. This prerequisite knowledge appeared to be lacking for Bert, which provided a deficiency learning impediment when it came to understanding the teaching on electrolysis.

Read about learners' alternative conceptions