Category: teaching model

A chemical bond would have to be made of atoms

Keith S. Taber

Amy was a participant in the Understanding Science Project. When I had talked to Amy when she was in Y10 she had referred to things being bonded: "where one thing is joined on to another thing, and it can be chemically bonded" and how "in a compound, where two or more elements are joined together, that's an example of chemical bonding".

The following year, in Y11, when she was studying fats she talked about "how they're made up and like with all the double bonds and single bonds" where a double bond was "where there are kind of like two bonds between erm carbon atoms instead of like one" and a bond was "how two atoms are joined together". Later in Y11, Amy told be that she did not know how to explain chemical bonding, but "in lessons like we've always been shown these kind of – things – where you kind of, you've got the atom, and then you've got the little, grey stick things which are meant to be the bonds, and you can just – fit them together."

Source: Image by WikimediaImages from Pixabay

As Amy had told me "everything is made up of atoms", I provocatively asked her if the chemical bond was made of atoms. Amy had "absolutely no idea" but she "suppose(d) it would have to be, wouldn't it".

Not only is this an alternative conception, but to a chemist, or science teacher, the idea that chemical bonds are themselves made up of atoms seems incongruous and offers a potential for infinite regress (are those atoms in the bonds, themselves bonded? If so, are those bonds also made of atoms?)

This alternative conception could be considered a kind of associative learning impediment – that is where a learner makes an unintended link and so applies an idea outside of its range of application. All material is considered to be made of atoms – or at least quanticles comprising one of more nuclei bound to electrons (i.e., ions, molecules). Even this is not an absolute: the material formed immediately after the big bang was not of this form, and nor is the matter in a neutron star, but the material we usually engage with is considered to be made of atom-like units (i.e., ions, molecules).

But to suggest that Amy has made an inappropriate association seems a little unfair. Had Amy thought "all matter was made of atoms" and then suggested that chemical bonding was made of atoms this would be inappropriate as chemical bonding is not material but a process – electrical interactions between quanticles. Yet it is hard to see how one can over-extend the range of 'everything', as in "everything is made up of atoms".

There is an inherent problem with the motto everything is made up of atoms. It is probably something that teachers commonly say, and think is entirely clear – that it is obvious what its scope is – but from the perspective of a student there is not the wealth of background knowledge to appreciate the implied limits on 'everything'.

Learners will readily pick up teaching mottos such as "everything is made of atoms" and take them quite literally: if everything is made of atoms then bonds must be made of atoms. So although she was wrong, I think Amy was just applying something she had learnt.

Ionic bonding – where the electron's transferred to complete the outer shell

Keith S. Taber

Amy was a participant in the Understanding Science Project. The first time I talked to Amy, near the start of her GCSE 'triple science' course in Y10 she told me that "in normal chemistry (i.e., the chemistry part of 'double science', as opposed to the optional additional chemistry lesson as part of 'triple science' that Amy also attended) we're doing about ionic bonding" which was "atoms which have either lost or gained electrons so they are either positively or negatively charged" and

"how the outer electron's transferred…to complete the outer shell of the erm chlorine, thing, ion…and the sodium atom loses erm, one electron is it, yeah one electron, erm, which the chlorine atom gains, and that yeah that completes its outer shell and makes the sodium positively charged and the chlorine negatively charged".

Amy told me that "in ionic bonding it's the electrons that are transferred, I think."

So Amy had acquired a common alternative conception, i.e. that ionic bonding involved electron transfer, and that this occurs to atoms to complete their electron shells.

Ionic bonding refers to the forces between ions that hold the structure of an ionic substance together, rather than a mechanism by which such ions might hypothetically be formed – yet often learners come away form learning about ionic bonding identifying it with a process of electron transfer between atoms instead of interactions between ions which can be used to explain the properties of ionic substances.

Moreover, the hypothetical electron transfer is a fiction. In the case of NaCl such an electron transfer between isolated Na and Cl atoms would be energetically unfavourable, even if reactants containing discrete atoms were available (which is unrealistic).

Whether students are taught that ionic bonding is electron transfer is a moot point, but often introductory teaching of the topic focuses not on the nature of the bonding, but on presenting a (flawed) teaching model of how the ions in the ionic structure could form by electron transfer between atoms. As this mechanism is non-viable, and so not an authentic scientific account, it may seem odd that teachers commonly offer it.

One explanation may simply be custom or tradition has made this an insidious alternative conception. Science teachers and textbooks have 'always' offered the image of electron transfer as representing ionic bonding. So, this is what new teachers had themselves been taught at school, is what they often see in textbooks, and so what they learn to teach.

Another possible explanation is in terms of what what is known as the atomic ontology. This is the idea that the starting pint for thinking about chemistry at the submicroscopic level is atoms. Atoms do not need to be explained (as if in nature matter always starts as atoms – which is not the case) and other entities such as ions and molecules do need to be explained in terms of atoms. So, the atomic ontology is a kind of misleading alternative conceptual framework for thinking about chemistry at the submicroscopic level.

Current only slows down at the resistor

Current only slows down at the resistor – by analogy with water flow 

Keith S. Taber

Students commonly think that resistance in a circuit has local effects, and in part that is because forming a mental model of what is going on in circuits is very difficult. Often models and analogies can be useful. However when an analogy is used in teaching there is also the potential for it to mislead.

Amy was a participant in the Understanding Science Project. Amy (when in Y10) told me she had been taught to use a water flow analogy for electric current. However, because her visualisation of what happens in water circuits was incorrect, she used the analogy to inform an alternative conception about circuits:

Do you have any kind of imagined sort of idea, any little mental models, about what (the flow of electricity round the circuit) might look like? Do you have a way of imagining that?

Erm, yeah, we've been taught the water tank and pipe running round it. … just imagine the water like flowing through a pipe, and obviously like, if the pipe becomes smaller a one point, erm, the water flow has to slow down, and that's meant to represent the resistance of something.

So, so if I had my water, er, tank and I had a series of pipes, they'd be water flowing through the pipes, and if I had a narrower pipe at one point, what happens then?

The water would have to slow down.

So would it slow down just as it goes through the narrow pipe, or would it slow down all the way round?

Erm – just through that part.

(Amy does not appreciate the implications of conservation of mass {that is, the continuity principle} here – at steady state there cannot be a greater mass flow at different points in the circuit).

…

And so how do you imagine that's got to do with resistance, how does that help you understand resistance?

…well resistance, it slows the current down, but then erm, once it passes a resistor or something it, the current is free to flow through the wire again

Analogies can be very useful teaching tools, but when using them it is important to check that the students already understand the features of the analogue that are meant to be helpful. It is also important to ensure that they understand which features are meant to be mapped onto the target system they are learning about, and which are not relevant.

Analogies are only useful when the learner has a good understand of the analogue. In this case, as Amy did not appreciate that the water flow throughout the system would be limited by the constriction, she could not use that as a useful analogy for why a resistor influences current flow at all points in a series circuit. This is an example of where a teaching model meant to support learning, which actually misleads the learner. That is, for Amy, with her flawed understanding of fluid flow, the teaching model acted as a pedagogic learning impediment – a type of grounded learning impediment.